Poker can I make a move if I feel my opponent might b making a move(but I'm basing this in timing)?

So basically I'm saying when I thinkmy opponent makes a move on me I'm basing it on timing as I feel because i have made moves on him in the past I feel he's probably getting anoyed so he's making a move... Or is just not a good play because it's more feel and guess work than anything else?...